1 ) absorption and HCL, inhibit its catalytic automatically . Such stabilizers include lead salts , organic acids, metal soaps , organic tin compounds , epoxy compounds , phenol salts and metal thiolate salt. They can react with HCL , inhibition PVC de HCL response.
2 ) replacement of PVC molecules suppress unstable allylic chlorine atoms off the PVC. Such as organic tin stabilizer of PVC unstable molecule ligand binding chlorine atoms in the ligand , a chlorine atom with an unstable organotin substitution .
3 ) the addition reaction of dibasic
lead stearate a polyene structure , a large conjugated system damage formation and reduce coloration . A salt of an unsaturated acid or ester containing double bonds , and the PVC molecules conjugated diene double bond addition reaction , thereby destroying the conjugated structure, and color.
4 ) to capture free radicals and prevent the oxidation reaction . Such as adding phenolic heat stabilizers can block off the HCL, is due to give phenol H atom radical degradation of PVC macromolecules with radical coupling reaction with O2 to form a substance can not be , and has a thermal stability. Such thermal stabilizers may have one or several functions of both .
Ideal PVC heat stabilizer should be a multi-functional substance , or a mixture of some materials , they can achieve the following functions: First, replacement lively, unstable substituent ; second is to absorb and neutralize the release of PVC during processing HCL, eliminating the autocatalytic degradation of the HCL ; third neutralization or passivation of the PVC
stabilizer for fittings catalytic metal ions from the degradation and other harmful impurities ; Fourth, through the chemical reaction forms an unsaturated bond can block the continued growth inhibition degradation coloring ; five is the best protection against ultraviolet radiation shielding effect . Typically heat stabilizers according to their performance with the use of special , rare cases used alone , and most varieties are powdery , some are highly toxic chemicals. For ease of use , to prevent dust poisoning, reduce toxic substances or replaced by non-toxic substances, at home and abroad in recent years developed many kinds of composite stabilizer , for example , the world famous German brand oxidized
PE WAX composite stabilizer Bear series , the United States , Germany, Japan, Netherlands and other countries or organotin compound organotin stabilizers have considerable market share in China . Therefore , efforts to promote the application developed in China with high efficiency , low cost , no dust pollution and non-toxic or low toxicity of new composite stabilizer , is the urgent need for the development of the plastics industry .
WSD Chemical is specificaitonal manufacturing plastic chemical in china for 10 years,WSD plastic processing aid and supply all kinds plasic chemicals ,PVC processing aid such as Metal soaps, PVC heat stabilizers,PVC plasticizer, processing aid Impact modifier, processing aid ,flame retardant, pigments and optical brightener.Metal soaps, PVC heat stabilizers,PVC plasticizer, Impact modifier, processing aid ,flame retardant, pigments and optical brightener.
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