Lubricant is a broad concept. According to their different functions, the lubricant for the following three categories: (1) to reduce the friction between the particles to improve the powder flowability of the materials, also known as glidants glidants); (2) to prevent the fluorescent brightener adhesion of raw materials to punch surface of the material, also known as anti-adhesion agent antiadherents); (3) to reduce the particle or tablet) with the friction between the die hole wall accessories, this is the real sense of the lubricant. An ideal lubricant should be both of the flow aid, anti-sticking and lubrication three roles, the lubricant in the currently available yet no such ideal lubricant, are often one or two aspects of a relatively good performance, but other effects are relatively poor.
Type of dispersant
Fatty acids, fatty amides, and esters
Stearamide and used with higher alcohol can improve lubricity and thermal stability, the amount (mass fraction) 0.3% -0.8%, the slip agent may be polyolefin; hexenyl bis hard fat acid amides, also known as ethylene bis-stearamide (EBS), the lubricant is a high melting point, the amount of 0.5% to 2%; glyceryl monostearate (GMS), glyceryl tristearate (HTG); oleic acid 0.2% to 0.5% of the amount; hydrocarbon wax solid, mp 57 ~ 70 ℃, insoluble in water, soluble in an organic solvent, the resin dispersibility, compatibility, heat stability are poor, the dosage is generally 0.5% or less
Paraffin
Although the wax is external lubricant, but straight-chain non-polar hydrocarbon, not wet the metal surface, such as polyvinyl chloride resin that does not prevent adhesion of metal walls, only, and stearic acid, calcium stearate and used, in order to achieve synergy
(Nujol): Freezing Point -15 ¯ -35 ℃, the extrusion and injection molding processing, the poor compatibility with the resin, add the amount is generally 0.3% to 0.5%, too much time, but the processing performance bad Microcrystalline wax: obtained from petroleum refining process, the PVC profile stabilizer larger molecular weight, and has many isomers, mp 65-90 ℃, lubricity and thermal stability, but poor dispersion, the dosage is generally 0.1% -0.2%, preferably butyl stearate, higher fatty acids, metal soaps with
Metal salts of higher fatty acids, called metal soaps such as barium stearate (BaSt) for a variety of plastics, an amount of about 0.5%; zinc stearate (ZnSt) for polyolefins, ABS, etc., the amount of was 0.3%; calcium stearate (CaSt) suitable for GE Plastics, external lubrication, the amount of 0.2% ¯ 1.5%; Other stearic acid soaps such as cadmium stearate (CdSt), stearic acid Magnesium (MgSt), copper stearate (CuSt) low molecular weight waxes
Based on a variety of low molecular aluminum hydroxide weight polyethylene wax (homopolymer or copolymer), polypropylene, polystyrene or other polymer modified as raw material, by pyrolysis, oxidation from a range of performance of different oligomers Its main products are: homopolymer, oxidized homopolymer, ethylene - acrylic acid copolymer, ethylene - vinyl acetate copolymer, low molecular weight ionomers five categories. Among the most commonly used polyethylene wax
Commonly used polyethylene wax average relative molecular mass of 1500-4000, the softening point of 102 ℃; Other specifications of polyethylene wax average relative molecular mass of 10,000 to 20,000, a softening point of 106 ℃; oxidized polyethylene wax of long-chain molecules with a certain amount of ester group or a soap, and thus the PVC, PE, PP, ABS and external lubrication more balanced, better, its transparency is good. As dispersing agent and its environment, many practical applications, selection of the appropriate dispersing agent is very important.
WSD Chemical is specificaitonal manufacturing plastic chemical in china for 10 years,WSD plastic processing aid and supply all kinds plasic chemicals ,PVC processing aid such as Metal soaps, PVC heat stabilizers,PVC plasticizer, processing aid Impact modifier, processing aid ,flame retardant, pigments and optical brightener.Metal soaps, PVC heat stabilizers,PVC plasticizer, Impact modifier, processing aid ,flame retardant, pigments and optical brightener.
2013年10月25日星期五
some description depolymerization pigment
In the dispersion process, only the surface of the secondary particles is not enough to wet paints, because such a large size, small surface area of the pigment particles forming group can not meet the requirements of paints and maintaining a stable dispersion state of liquid paint .
Must therefore be subjected to PVC heat stabilizer external mechanical forces (shear forces primarily) deaggregation these large particles, to restore back to the original level at or near the particle size to small particles form a large surface area exposed to the paint and so that all surfaces are exposed by wet paints.
This means the applied mechanical force, the pigment agglomerates and aggregates restored or nearly restored to the original level of particles or depolymerization process called dispersion process called.
Pigment in the paint in the paint manufacturing process depolymerization is the main, the most energy consuming processes. Make pigment depolymerization external mechanical force, usually by grinding and dispersion we normally use equipment, such as a sand mill, ball mill, three-roll machine, high speed disperser and two roll machine generated.
As a dispersion medium in order to create a liquid vehicle for the pigment (filling) material particles penetrate the surface of the conditions necessary to color (fill) material aggregates and agglomerates can be applied to promote its breakdown external mechanical force, the color (fill) depolymerization material particles, it is better to paint the wetting liquid, which requires grinding and dispersion equipment.
Paint the polishing slurry, the pigment particles depolymerization process, not only can be sufficiently liquid so that wet paint color (fill) material particle surface to improve the stability of the millbase, and with a higher level of pigment dispersion, coloring pigments, cover will be a corresponding increase in strength, gloss and other paint film performance is also improved. So the selection of an efficient grinding and aluminum stearate dispersion device, can greatly improve the dispersion of pigment in the paint level, thereby improving the millbase while reducing the amount of pigment stability, improve the quality of paint and coatings.
3, stabilization:
Depolymerization has been wetted pigment particles distributed to a large number of paints continue to go, so there is enough paint coated on the periphery of pigment particles, and isolated from one another, thereby reducing the attractive force between the pigment particles, to avoid the mutual contact between the pigment particles, such that each has to be gathered and the solution of the pigment particles are moistened sufficiently thick, continuous, non-volatile dispersion of film-forming material is permanently open, the dispersion applied in the absence of under the control of mechanical forces, the pigment particles will not appear again coalesce into large particles in the process, called the stabilization process, to obtain stability of the pigment dispersion, the purpose is production of the final paint.
Thus, the dispersion of pigment in the paint is wet, and stabilization depolymerization process three major components.
But, in fact, these three processes are not calcium zinc stabilizer completely separate, but simultaneous and alternating conducted. For dispersing the pigment in the paint dispersion is formed, the relationship between the three: a wet basis, in order to more fully depolymerization wetting, and to achieve steady state of the ultimate goal.
If the pigment is dispersed in the paint well, to reach a relatively stable state, then had been dispersed pigment particles likely will re-close and gathered into large particles, forming what we call a pigment floc flocculation of pigments is distributed among the inverse process.
Floc pigments and aggregates and agglomerates, although the original-sized particles made of large particle coalescence particle group, but the floc and the latter are essentially different, although it still paints the surface of the package cover, paint particles have been filled the gap, the pigment aggregates and agglomerates the surface of the cladding is air and water, the gap is filled by air, but the micro-flocculation state, in the production of coatings as well as its the use of the Department.
Must therefore be subjected to PVC heat stabilizer external mechanical forces (shear forces primarily) deaggregation these large particles, to restore back to the original level at or near the particle size to small particles form a large surface area exposed to the paint and so that all surfaces are exposed by wet paints.
This means the applied mechanical force, the pigment agglomerates and aggregates restored or nearly restored to the original level of particles or depolymerization process called dispersion process called.
Pigment in the paint in the paint manufacturing process depolymerization is the main, the most energy consuming processes. Make pigment depolymerization external mechanical force, usually by grinding and dispersion we normally use equipment, such as a sand mill, ball mill, three-roll machine, high speed disperser and two roll machine generated.
As a dispersion medium in order to create a liquid vehicle for the pigment (filling) material particles penetrate the surface of the conditions necessary to color (fill) material aggregates and agglomerates can be applied to promote its breakdown external mechanical force, the color (fill) depolymerization material particles, it is better to paint the wetting liquid, which requires grinding and dispersion equipment.
Paint the polishing slurry, the pigment particles depolymerization process, not only can be sufficiently liquid so that wet paint color (fill) material particle surface to improve the stability of the millbase, and with a higher level of pigment dispersion, coloring pigments, cover will be a corresponding increase in strength, gloss and other paint film performance is also improved. So the selection of an efficient grinding and aluminum stearate dispersion device, can greatly improve the dispersion of pigment in the paint level, thereby improving the millbase while reducing the amount of pigment stability, improve the quality of paint and coatings.
3, stabilization:
Depolymerization has been wetted pigment particles distributed to a large number of paints continue to go, so there is enough paint coated on the periphery of pigment particles, and isolated from one another, thereby reducing the attractive force between the pigment particles, to avoid the mutual contact between the pigment particles, such that each has to be gathered and the solution of the pigment particles are moistened sufficiently thick, continuous, non-volatile dispersion of film-forming material is permanently open, the dispersion applied in the absence of under the control of mechanical forces, the pigment particles will not appear again coalesce into large particles in the process, called the stabilization process, to obtain stability of the pigment dispersion, the purpose is production of the final paint.
Thus, the dispersion of pigment in the paint is wet, and stabilization depolymerization process three major components.
But, in fact, these three processes are not calcium zinc stabilizer completely separate, but simultaneous and alternating conducted. For dispersing the pigment in the paint dispersion is formed, the relationship between the three: a wet basis, in order to more fully depolymerization wetting, and to achieve steady state of the ultimate goal.
If the pigment is dispersed in the paint well, to reach a relatively stable state, then had been dispersed pigment particles likely will re-close and gathered into large particles, forming what we call a pigment floc flocculation of pigments is distributed among the inverse process.
Floc pigments and aggregates and agglomerates, although the original-sized particles made of large particle coalescence particle group, but the floc and the latter are essentially different, although it still paints the surface of the package cover, paint particles have been filled the gap, the pigment aggregates and agglomerates the surface of the cladding is air and water, the gap is filled by air, but the micro-flocculation state, in the production of coatings as well as its the use of the Department.
2013年10月24日星期四
alum water principle and its preparation method of aluminum sulfate
Alum is a familiar folk purifying agent , which is a kind of aluminum sulfate and potassium sulfate complex salt . Then it is how to use water purification , and its use What is the principle . But also how to use it produced . We together look.
Alum water principle
Alum can be ionized in water, two metal ions : KAl (SO4) 2 = K + + Al3 + + 2SO4 4 -. And Al3 + is easily hydrolyzed carbon black powder to form colloidal aluminum hydroxide Al (OH) 3: Al3 + + 3H2O = Al (OH) 3 ( gel ) + 3H +. Aluminum hydroxide colloid strong adsorption capacity , can absorb impurities suspended in the water , and the precipitate formed , the water clarification. Therefore , a better purifying agent is alum .
Aluminum sulfate alum was prepared using 1 , aluminum sulfate is added in an excess of ammonia , to obtain aluminum hydroxide precipitate potassium sulfate and ammonium sulfate solution, a 2 , a solid aluminum hydroxide was filtered , washed with dilute sulfuric acid obtained by adding an appropriate amount of aluminum sulfate , evaporation and iron oxide yellow crystallization 3 , to the filtrate was added an excess of potassium hydroxide and heated , the ammonia evaporated to give potassium sulfate solution , evaporation and crystallization . Due to the use of the prepared aluminum sulfate alum ( potassium aluminum sulfate ) will affect the body iron, calcium absorption components , leading to osteoporosis , anemia, and even affect the development of nerve cells . Therefore , it is now generally used for drinking water alum . Of course, the same rationale containing aluminum ions chloride, aluminum chloride is not used for drinking water purification.
Alum water principle
Alum can be ionized in water, two metal ions : KAl (SO4) 2 = K + + Al3 + + 2SO4 4 -. And Al3 + is easily hydrolyzed carbon black powder to form colloidal aluminum hydroxide Al (OH) 3: Al3 + + 3H2O = Al (OH) 3 ( gel ) + 3H +. Aluminum hydroxide colloid strong adsorption capacity , can absorb impurities suspended in the water , and the precipitate formed , the water clarification. Therefore , a better purifying agent is alum .
Aluminum sulfate alum was prepared using 1 , aluminum sulfate is added in an excess of ammonia , to obtain aluminum hydroxide precipitate potassium sulfate and ammonium sulfate solution, a 2 , a solid aluminum hydroxide was filtered , washed with dilute sulfuric acid obtained by adding an appropriate amount of aluminum sulfate , evaporation and iron oxide yellow crystallization 3 , to the filtrate was added an excess of potassium hydroxide and heated , the ammonia evaporated to give potassium sulfate solution , evaporation and crystallization . Due to the use of the prepared aluminum sulfate alum ( potassium aluminum sulfate ) will affect the body iron, calcium absorption components , leading to osteoporosis , anemia, and even affect the development of nerve cells . Therefore , it is now generally used for drinking water alum . Of course, the same rationale containing aluminum ions chloride, aluminum chloride is not used for drinking water purification.
PAFC first three outs coagulation process
PAFC is aluminum ( aluminum sulfate ) and iron coagulation hydrolysis , and set them on the merits of a new and efficient coagulant It is also the wastewater treatment coagulant. Well, you know ferric chloride coagulation in the first three kind of how it is played . We dibasic lead stearate take a look at three stages of the coagulation process and the formation of hydraulic conditions alum status .
Condensed phases: the liquid is injected into the raw water coagulation tank with rapid coagulation in a very short period of time the process of forming a fine alum , when the water becomes more turbid , it requires water to produce intense turbulence . Beaker experiment should be fast ( 250-300 rev / min ) was stirred for 10-30S, generally no more than 2min.
Flocculation stages: yes alum n-butyl stearate grow thicker process, requiring an appropriate degree of turbulence and sufficient residence time (10-15min), to the later observed sinking slowly gathered a large number of alum to form a clear surface layer . Beaker experiment first with 150 rev / min stirring for about 6 minutes, then 60 cycles / minute to about 4 minutes was stirred in suspension .
Settlement stage : it is carried out in the settlement pool floc settlement process , requiring slow water flow , to improve the general efficiency of the use of ramps ( plate ) settling pond , lots of thick alum perianth inclined tube ( plate ) and deposited in the glyceryl monostearate pool wall barrier end of the upper water to clarify the water , the rest of the small particle size, density alum side down slowly , while continuing to collide knot large cloud -to-late I basically unchanged . Beaker experiments should be 20-30 rev / min slow stirring for 5 minutes, then 10 minutes of static sink , than measured turbidity . PAFC take aluminum ( such as aluminum sulfate , etc. ) , iron coagulant their respective flotation operation advantageous to improve the PAC coagulation performance ; the high turbidity water and low temperature and low turbidity water purification effect is particularly evident not add alkaline additives or other coagulant .
Condensed phases: the liquid is injected into the raw water coagulation tank with rapid coagulation in a very short period of time the process of forming a fine alum , when the water becomes more turbid , it requires water to produce intense turbulence . Beaker experiment should be fast ( 250-300 rev / min ) was stirred for 10-30S, generally no more than 2min.
Flocculation stages: yes alum n-butyl stearate grow thicker process, requiring an appropriate degree of turbulence and sufficient residence time (10-15min), to the later observed sinking slowly gathered a large number of alum to form a clear surface layer . Beaker experiment first with 150 rev / min stirring for about 6 minutes, then 60 cycles / minute to about 4 minutes was stirred in suspension .
Settlement stage : it is carried out in the settlement pool floc settlement process , requiring slow water flow , to improve the general efficiency of the use of ramps ( plate ) settling pond , lots of thick alum perianth inclined tube ( plate ) and deposited in the glyceryl monostearate pool wall barrier end of the upper water to clarify the water , the rest of the small particle size, density alum side down slowly , while continuing to collide knot large cloud -to-late I basically unchanged . Beaker experiments should be 20-30 rev / min slow stirring for 5 minutes, then 10 minutes of static sink , than measured turbidity . PAFC take aluminum ( such as aluminum sulfate , etc. ) , iron coagulant their respective flotation operation advantageous to improve the PAC coagulation performance ; the high turbidity water and low temperature and low turbidity water purification effect is particularly evident not add alkaline additives or other coagulant .
2013年10月21日星期一
types of plastic flame sense
Plastic inexhaustible extended use category while its volume increases and flammable and easily ignited a fever , brought to mankind unexpected danger and loss . Began as a flame retardant additive major categories beginning in chemical fiber, plastics industry projections . Brominated flame retardants despite heavy smoke , because of environmental problems by Glycrin monostearate the EU restrictions ; But since retardant properties, and with less impact on product performance is small, quite a long time thereafter remain within the main flame . Tips progress along the international growth of brominated flame retardants new features is a continuous and progressive increase of bromine content (fèn) molecular weight . Most phosphorus flame retardants (dū) is a liquid , mainly used for PU, PVC and other plastics . Small molecule phosphorus flame retardant main problems are volatile , high heat resistance is not high , now is trying to develop a large molecular weight compounds and oligomers , special suitable for casting finished and soft PU foam guessed . Flame retardant and plasticizer , flame retardant and cross-linked multi- phosphorus flame retardant effect acrylic processing of the growth is another major aspect is the low temperature flame-retardant plasticizer special probation plasticized PVC is mainly used in the finished product , such as domestic cumene produced two phosphate. Flame number which reflects the activity of the crosslinking agent is a phosphorus-containing polyhydric alcohols , not only as a reflection type flame retardant PU , and also with the brominated flame retardant and used epoxy resin , brominated flame retardant can be greatly reduced dosage . Since phosphorus flame retardant but also to the low toxicity of growth , not only to solve their toxic products , but also to consider the toxicity of the combustion product differentiation and waste pollution problem situations , or even appropriate, production, sales , storage and transportation process (dì) toxicity problems. Aluminum hydroxide usually with a silane coupling agent , titanate coupling agent and stearic acid ( salt ) , etc. before disposal , just started this titanium dioxide country , foreign countries have been further carried out before the new special effect modifier of aluminum hydroxide open up. Solem new technology company with a silane disposal and disposal of organic silicone coated aluminum hydroxide , in the PP, PE is added to 70% volume of 60 processing still very good , and the physical properties and flame retardancy of progress.
Inorganic synergist new varieties. A small amount of aluminum hydroxide flame retardant synergist can fill data function has obvious improvements , such as restraint dripping , improved mechanical properties . And aluminum hydroxide can play a synergistic role in a wide scope of an inorganic flame retardant synergist , mainly metal oxides and zinc borate , phosphorus-based compound ( red phosphorus , phosphate) , a silicon -based compound, a metal nitrate ( copper nitrate , silver nitrate ) , ammonium polyphosphate , etc. .
Inorganic synergist new varieties. A small amount of aluminum hydroxide flame retardant synergist can fill data function has obvious improvements , such as restraint dripping , improved mechanical properties . And aluminum hydroxide can play a synergistic role in a wide scope of an inorganic flame retardant synergist , mainly metal oxides and zinc borate , phosphorus-based compound ( red phosphorus , phosphate) , a silicon -based compound, a metal nitrate ( copper nitrate , silver nitrate ) , ammonium polyphosphate , etc. .
Some of the main flame retardant plastic description
Flame retardants
Most plastics are flammable . With the plastic in the construction, furniture, transportation, aviation , aerospace , electrical and other aspects of the widely used to improve the flame retardancy of plastics has carbon black powder become a very urgent issue. Inhibiting polymer flame retardant is a class of flammability additives, they are mostly of the Periodic Table Ⅴ, Ⅶ Ⅲ elements and compounds ; especially phosphorus , bromine , chlorine , antimony and aluminum compounds. Sub- additive flame retardants and reactive types . Flame retardant halogen-containing primarily phosphate and Acrylic processing aid phosphate, a halogenated hydrocarbon , antimony oxide , and aluminum hydroxide . Advantage is easy to use and adaptable . However, the addition of capacity of 10 % to 30% , often affect the performance of plastics . Reactive flame retardant containing the elements actually monomer, it has little effect on the plastic properties . Common reactive flame retardants , halogenated anhydrides such as for polyesters , for epoxy resins of tetrabromobisphenol A, and phosphorus for polyurethane polyol. Flame , the current amount of second plasticizer. Consuming most varieties of plastic flame retardant polyvinyl chloride, polystyrene, polyurethane foam , unsaturated polyester , ABS resin and polypropylene.
Most plastic is flammable , its titanium dioxide anatase products, which brought a lot of application security risks. Precisely, flame retardants, flame retardants known as more appropriate , because " flame " contains two meanings flame retardant and smoke suppression , compared with the broader concept of flame retardants . However , long time, people have become accustomed to the concept of use of flame retardants
Most plastics are flammable . With the plastic in the construction, furniture, transportation, aviation , aerospace , electrical and other aspects of the widely used to improve the flame retardancy of plastics has carbon black powder become a very urgent issue. Inhibiting polymer flame retardant is a class of flammability additives, they are mostly of the Periodic Table Ⅴ, Ⅶ Ⅲ elements and compounds ; especially phosphorus , bromine , chlorine , antimony and aluminum compounds. Sub- additive flame retardants and reactive types . Flame retardant halogen-containing primarily phosphate and Acrylic processing aid phosphate, a halogenated hydrocarbon , antimony oxide , and aluminum hydroxide . Advantage is easy to use and adaptable . However, the addition of capacity of 10 % to 30% , often affect the performance of plastics . Reactive flame retardant containing the elements actually monomer, it has little effect on the plastic properties . Common reactive flame retardants , halogenated anhydrides such as for polyesters , for epoxy resins of tetrabromobisphenol A, and phosphorus for polyurethane polyol. Flame , the current amount of second plasticizer. Consuming most varieties of plastic flame retardant polyvinyl chloride, polystyrene, polyurethane foam , unsaturated polyester , ABS resin and polypropylene.
Most plastic is flammable , its titanium dioxide anatase products, which brought a lot of application security risks. Precisely, flame retardants, flame retardants known as more appropriate , because " flame " contains two meanings flame retardant and smoke suppression , compared with the broader concept of flame retardants . However , long time, people have become accustomed to the concept of use of flame retardants
2013年10月10日星期四
Analysis of the use of natural red iron oxide
Iron oxide red do you know? Professionals may be more familiar with such items. Today we'll learn a wide range of uses of natural iron oxide red! Look at it together!
Red iron oxide has both natural and Metal stearate artificial. West said the natural red. A substantially pure iron oxide. Red powder. As production methods and operating conditions, their crystal structure and physical properties are very different, color changes from orange to blue to violet light between. Hiding power and tinting strength are great. There are excellent light, high temperature performance and resistance to atmospheric effects, resistance to dirty gas, all the alkali resistance. Only in optical brightener concentrated acid under heating was gradually dissolved.
Natural red iron oxide has good coloring power, the production of ultra-fine natural red iron oxide pigments, the main chemical ingredient, fine texture, pure color, particle size distribution science, measured by the Chinese Institute of Chemical Industry Metals data indicate that, in similar products , it is non-toxic, high temperature, not with acid, alkali, salt effect, is replaced Hongdan green pigments. Surface to be easily attached to dust, Every time there was rain Xueshuang, more so the film surface scrub as new, soft lead stearate colors and elegant, do not fade, change color, replace part of red iron oxide. Natural red iron oxide is mainly used for the production of iron red paint industry series primer, paint, mixed paint and high-grade paint colors such species or building components for color, natural red iron oxide can replace the roots of materials and precipitated barium sulfate , talc and other fillers. ...
Red iron oxide has both natural and Metal stearate artificial. West said the natural red. A substantially pure iron oxide. Red powder. As production methods and operating conditions, their crystal structure and physical properties are very different, color changes from orange to blue to violet light between. Hiding power and tinting strength are great. There are excellent light, high temperature performance and resistance to atmospheric effects, resistance to dirty gas, all the alkali resistance. Only in optical brightener concentrated acid under heating was gradually dissolved.
Natural red iron oxide has good coloring power, the production of ultra-fine natural red iron oxide pigments, the main chemical ingredient, fine texture, pure color, particle size distribution science, measured by the Chinese Institute of Chemical Industry Metals data indicate that, in similar products , it is non-toxic, high temperature, not with acid, alkali, salt effect, is replaced Hongdan green pigments. Surface to be easily attached to dust, Every time there was rain Xueshuang, more so the film surface scrub as new, soft lead stearate colors and elegant, do not fade, change color, replace part of red iron oxide. Natural red iron oxide is mainly used for the production of iron red paint industry series primer, paint, mixed paint and high-grade paint colors such species or building components for color, natural red iron oxide can replace the roots of materials and precipitated barium sulfate , talc and other fillers. ...
Iron oxide red pigment
Red iron oxide, may be relatively well-known professionals. But we usually see red items, many of which are red iron oxide as raw material. Then, together we know about.
Iron oxide red pigment:
1, iron oxide red pigment Iron Oxide Red for potassium stearate coloring plastics, such as thermosets and thermoplastics, and rubber products, coloring, such as automobile inner tubes, aircraft inner tube, bicycle inner tube and so on. 2, iron oxide red pigment Iron Oxide Red for a variety of paint color and protective substances, including water-based interior and exterior paints, powder coatings, etc.; also apply to oil paint, including epoxy, alkyd, amino and other primer and surface paint; also be used for toy paint, decorative paint, furniture paint, electrophoretic lacquers and enamels.
3, iron oxide red pigment in the various types of precast concrete products and building materials as pigments or PVC impact modifier coloring agents, directly into the application of cement. A variety of indoor and outdoor color concrete surfaces, such as walls, floors, ceilings, pillars, porches, roads, parking lots, stairs, stations, etc.; various architectural ceramics and glass ceramics, such as tiles, floor tiles, roof tiles, panels , terrazzo, mosaic tiles, artificial marble.
4, red iron oxide commonly used in construction, rubber, plastics, paint and other industries, particularly iron oxide red primer with rust function, you can replace the expensive red lead paint, saving non-ferrous metals. High Ground material, for use in precision metal instruments, optical glass polishing. Powder metallurgy high purity is the main base for various magnetic alloy smelting and other senior alloy steels. By the one pack stabilizer ferrous sulfate or iron oxide yellow, or scraps of iron mixed by high temperature calcination, or directly from the liquid medium is made.
5, red in the building materials industry, mainly for color cement, colored cement tiles, colored cement tiles, imitation glazed tiles, concrete tiles, colored mortar, colored asphalt, terrazzo, mosaic tiles, artificial marble and stucco walls, etc.; in the paints and coatings industry is mainly used to manufacture a variety of paints, coatings, inks. In other industries, such as ceramics, rubber, plastics, leather, pulp used to make arrangements light coloring agent and a filler
Iron oxide red pigment:
1, iron oxide red pigment Iron Oxide Red for potassium stearate coloring plastics, such as thermosets and thermoplastics, and rubber products, coloring, such as automobile inner tubes, aircraft inner tube, bicycle inner tube and so on. 2, iron oxide red pigment Iron Oxide Red for a variety of paint color and protective substances, including water-based interior and exterior paints, powder coatings, etc.; also apply to oil paint, including epoxy, alkyd, amino and other primer and surface paint; also be used for toy paint, decorative paint, furniture paint, electrophoretic lacquers and enamels.
3, iron oxide red pigment in the various types of precast concrete products and building materials as pigments or PVC impact modifier coloring agents, directly into the application of cement. A variety of indoor and outdoor color concrete surfaces, such as walls, floors, ceilings, pillars, porches, roads, parking lots, stairs, stations, etc.; various architectural ceramics and glass ceramics, such as tiles, floor tiles, roof tiles, panels , terrazzo, mosaic tiles, artificial marble.
4, red iron oxide commonly used in construction, rubber, plastics, paint and other industries, particularly iron oxide red primer with rust function, you can replace the expensive red lead paint, saving non-ferrous metals. High Ground material, for use in precision metal instruments, optical glass polishing. Powder metallurgy high purity is the main base for various magnetic alloy smelting and other senior alloy steels. By the one pack stabilizer ferrous sulfate or iron oxide yellow, or scraps of iron mixed by high temperature calcination, or directly from the liquid medium is made.
5, red in the building materials industry, mainly for color cement, colored cement tiles, colored cement tiles, imitation glazed tiles, concrete tiles, colored mortar, colored asphalt, terrazzo, mosaic tiles, artificial marble and stucco walls, etc.; in the paints and coatings industry is mainly used to manufacture a variety of paints, coatings, inks. In other industries, such as ceramics, rubber, plastics, leather, pulp used to make arrangements light coloring agent and a filler
2013年10月9日星期三
PVC heat stabilizers catalysis
PVC heat stabilizers catalyst. Such stabilizers include lead salts , organic acids, metal soaps , organic tin compounds , epoxy compounds , phenol salts and metal thiolate salt. They can react with HCL , inhibition PVC de HCL response.
2 ) replacement of PVC molecules suppress Metallic stearate unstable allylic chlorine atoms off the PVC. Such as organic tin stabilizer of PVC unstable molecule ligand binding chlorine atoms in the ligand , a chlorine atom with an unstable organotin substitution . 3 ) the addition reaction of a polyene structure , a large conjugated system damage formation and reduce coloration . A salt of an unsaturated acid or ester containing double bonds , and the PVC molecules conjugated diene double bond addition reaction , thereby destroying the conjugated structure, and color.
4 ) to capture free radicals and prevent the oxidation reaction . Such as adding phenolic heat stabilizers can block off the HCL, is due to give phenol H atom radical degradation of PVC macromolecules with radical coupling reaction with O2 to form a substance can not be , and has a thermal stability. Such thermal stabilizers may have one or several functions of both .
Ideal PVC heat stabilizer should be a multi-functional substance , or a mixture of some materials , they can achieve the following functions: First, replacement lively, unstable substituent ; second is to absorb and neutralize the release of PVC during processing HCL, eliminating the autocatalytic degradation of the HCL ; third neutralization or passivation of the catalytic metal ions from the degradation and other harmful impurities ; Fourth, through the chemical reaction forms an unsaturated bond can block the PVC processing aid continued growth inhibition degradation coloring ; five is the best protection against ultraviolet radiation shielding effect . Typically heat stabilizers according to their performance with the use of special , rare cases used alone , and most varieties are powdery , some are highly toxic chemicals. For ease of use , to prevent dust poisoning, reduce toxic substances or replaced by non-toxic substances, at home and abroad in recent years developed many kinds of composite stabilizer , for example , the world famous German brand composite stabilizer Bear series , the United States , Germany, Japan, Netherlands and other countries or organotin compound organotin stabilizers have considerable market share in China . Therefore , efforts to promote the application developed in China with high efficiency , low cost , no dust pollution and non-toxic or low toxicity of new composite stabilizer , is the urgent need for the development of the plastics industry .
Ideal thermal stabilizer should also absorb HCL, remove the active site , the addition of a conjugated polyene chain , destruction carbenium salts and prevent auto-oxidation , etc. , which does not produce a product of catalytic degradation of PVC . The actual heat stabilizers with different functions due to exhibit different thermal stability characteristics ,
1 ) cadmium , zinc soap is typical of aluminium stearate early -type heat stabilizers , can quickly absorb HCL, and Cd, Zn in the catalyst to effectively replace PVC chain carboxylate unstable chlorine atom , thereby effectively suppressing the initial degradation and coloring , but because of consumption of fast transformation products CdC12, ZnC12, but also off the HCL PVC efficient catalysts , which will lead to degradation of the material PVC vicious suddenly darkened , so long-term thermal stability .
2 ) barium, calcium soap is a typical long-term thermal stabilizers, only the function of absorbing HCL , PVC can not effectively suppress coloration , but the transformation products BaC12, CaC12 non- catalytic activity , does not cause a sudden black PVC , long-term heat stability better.
2 ) replacement of PVC molecules suppress Metallic stearate unstable allylic chlorine atoms off the PVC. Such as organic tin stabilizer of PVC unstable molecule ligand binding chlorine atoms in the ligand , a chlorine atom with an unstable organotin substitution . 3 ) the addition reaction of a polyene structure , a large conjugated system damage formation and reduce coloration . A salt of an unsaturated acid or ester containing double bonds , and the PVC molecules conjugated diene double bond addition reaction , thereby destroying the conjugated structure, and color.
4 ) to capture free radicals and prevent the oxidation reaction . Such as adding phenolic heat stabilizers can block off the HCL, is due to give phenol H atom radical degradation of PVC macromolecules with radical coupling reaction with O2 to form a substance can not be , and has a thermal stability. Such thermal stabilizers may have one or several functions of both .
Ideal PVC heat stabilizer should be a multi-functional substance , or a mixture of some materials , they can achieve the following functions: First, replacement lively, unstable substituent ; second is to absorb and neutralize the release of PVC during processing HCL, eliminating the autocatalytic degradation of the HCL ; third neutralization or passivation of the catalytic metal ions from the degradation and other harmful impurities ; Fourth, through the chemical reaction forms an unsaturated bond can block the PVC processing aid continued growth inhibition degradation coloring ; five is the best protection against ultraviolet radiation shielding effect . Typically heat stabilizers according to their performance with the use of special , rare cases used alone , and most varieties are powdery , some are highly toxic chemicals. For ease of use , to prevent dust poisoning, reduce toxic substances or replaced by non-toxic substances, at home and abroad in recent years developed many kinds of composite stabilizer , for example , the world famous German brand composite stabilizer Bear series , the United States , Germany, Japan, Netherlands and other countries or organotin compound organotin stabilizers have considerable market share in China . Therefore , efforts to promote the application developed in China with high efficiency , low cost , no dust pollution and non-toxic or low toxicity of new composite stabilizer , is the urgent need for the development of the plastics industry .
Ideal thermal stabilizer should also absorb HCL, remove the active site , the addition of a conjugated polyene chain , destruction carbenium salts and prevent auto-oxidation , etc. , which does not produce a product of catalytic degradation of PVC . The actual heat stabilizers with different functions due to exhibit different thermal stability characteristics ,
1 ) cadmium , zinc soap is typical of aluminium stearate early -type heat stabilizers , can quickly absorb HCL, and Cd, Zn in the catalyst to effectively replace PVC chain carboxylate unstable chlorine atom , thereby effectively suppressing the initial degradation and coloring , but because of consumption of fast transformation products CdC12, ZnC12, but also off the HCL PVC efficient catalysts , which will lead to degradation of the material PVC vicious suddenly darkened , so long-term thermal stability .
2 ) barium, calcium soap is a typical long-term thermal stabilizers, only the function of absorbing HCL , PVC can not effectively suppress coloration , but the transformation products BaC12, CaC12 non- catalytic activity , does not cause a sudden black PVC , long-term heat stability better.
PVC heat stabilizers some of the important role
1 absorption and HCl, inhibit its catalytic automatically . Such stabilizers include lead salts , organic acids, metal soaps , organic tin compounds , epoxy compounds, amines, metal alkoxide and a phenolic salts and metal thiolate salt. They are available with HCl to de- HCl reaction inhibition PVC .
(2) replacement of PVC unstable allylic chlorine tin stabilizer molecule or a tertiary carbon atom chlorine atom , inhibit de PVC. Such as organic tin stabilizer of PVC unstable molecule of chlorine ligand binding occurs , the ligand , organic tin substitution with an unstable chlorine atoms . 3 with the addition reaction of a polyene structure , damage the formation of a large conjugated system and reduce coloration . A salt of an unsaturated acid or ester containing double bonds , and the PVC molecules conjugated diene double bond addition reaction , thereby destroying the Diethyleneglycoldibenzoate conjugated structure, and color.
4 capture free radicals and prevent the oxidation reaction . Such as adding phenolic heat stabilizers can block off HCl, is due to give phenol H atom radical degradation of PVC macromolecules with radical coupling reaction with O2 to form a substance can not be , and has a thermal stability. Such thermal stabilizers may have one or several functions of both . Ideal PVC heat stabilizer should be a multi-functional substance , or a mixture of some materials , they can achieve the following functions:
1 replacement lively , unstable substituent such titanium dioxide as attached to the tertiary Cl Cl atom or allyl chloride , to form a stable structure ;
(2) to absorb and process the PVC processing and release of HCl, HCl elimination autocatalytic degradation ;
3 passivated on the degradation neutralized or catalytic metal ions and other harmful impurities ;
4 by chemical reaction forms an unsaturated bond can block the continued growth inhibiting degradation coloring ;
5 The best protection against ultraviolet radiation shielding effect .
(2) replacement of PVC unstable allylic chlorine tin stabilizer molecule or a tertiary carbon atom chlorine atom , inhibit de PVC. Such as organic tin stabilizer of PVC unstable molecule of chlorine ligand binding occurs , the ligand , organic tin substitution with an unstable chlorine atoms . 3 with the addition reaction of a polyene structure , damage the formation of a large conjugated system and reduce coloration . A salt of an unsaturated acid or ester containing double bonds , and the PVC molecules conjugated diene double bond addition reaction , thereby destroying the Diethyleneglycoldibenzoate conjugated structure, and color.
4 capture free radicals and prevent the oxidation reaction . Such as adding phenolic heat stabilizers can block off HCl, is due to give phenol H atom radical degradation of PVC macromolecules with radical coupling reaction with O2 to form a substance can not be , and has a thermal stability. Such thermal stabilizers may have one or several functions of both . Ideal PVC heat stabilizer should be a multi-functional substance , or a mixture of some materials , they can achieve the following functions:
1 replacement lively , unstable substituent such titanium dioxide as attached to the tertiary Cl Cl atom or allyl chloride , to form a stable structure ;
(2) to absorb and process the PVC processing and release of HCl, HCl elimination autocatalytic degradation ;
3 passivated on the degradation neutralized or catalytic metal ions and other harmful impurities ;
4 by chemical reaction forms an unsaturated bond can block the continued growth inhibiting degradation coloring ;
5 The best protection against ultraviolet radiation shielding effect .
2013年10月8日星期二
PVC heat stabilizers and mechanism
PVC is the first ideal structure - tail structure-CH2-CHCl-CH2-CHCl-, is quite stable. But so far the PVC synthesis method can not be like synthetic butadiene rubber, as the role of catalyst in Jigger so there are rules for orientation cis butadiene polymerization is a free radical polymerization of vinyl chloride random polymerization, in addition to its stable First - tail structure, as well as the first - the first structure-CH2
-CHCl-CHCl-CH-, tail - tail structure-CHCl-CH2-CH2-CHCl-; generate a coupling disproportionation vinyl Results CH2 = CH-CHCl
-CH2-structure and allyl chloride-CH2-CH = CH-CHCl-CH2 and so on.
Generated in the PVC synthetic allyl chloride, chlorine and tertiary carbon double bond in its molecular chain structure instability, unstable cis
Sequence is: PVC within the molecular chain allyl chloride> tertiary carbon Chlorine> terminal allyl chloride> sec chlorine. PVC processing is easily degraded but because
The PVC molecular chain structure, there vegetable stearic acid is instability factors, such modification not be stabilized, and its decomposition temperature is about 130 ℃, but
PVC resin to be processed into useful articles, molding temperature to above 190 ℃. Therefore, you must add to its junction heat stabilizer
Improved structure for stabilization. Four types of heat stabilizers heat discoloration Comment
Ideal thermal stabilizer should also absorb HCL, remove the active site, the addition of a conjugated polyene chain, from the destruction of carbenium
Sub-salt, to prevent the auto-oxidation and other functions, without generating a catalytic degradation of PVC products. The plastic processing aid actual heat stabilizer due to
Has a different function and behave in a different thermal stability characteristics, can be divided into early-type, long type, intermediate type and versatile
Four categories.
1) cadmium, zinc soap is typical of early-type heat stabilizers, can quickly absorb HCL, and Cd, Zn in the catalyst effectively carboxylic
Replace PVC chain radical unstable chlorine atoms, thereby effectively suppressing the initial degradation and coloring, but because of consumption of fast transformation products CdC12, ZnC12, but also off the HCL PVC efficient catalysts, which will lead to the aluminium distearate degradation of PVC material suddenly becomes a vicious black, so
Long-term thermal stability. 2) barium, calcium soap is a typical long-term thermal stabilizers, absorption HCL function only and therefore can not effectively suppress coloring PVC,
But the transformation products BaC12, CaC12 does not have catalytic activity, does not cause a sudden black PVC, long-term thermal stability. 3) fatty acids, organic tin are intermediate, both absorbs HCL, can effectively replace PVC with chain carboxylate unstable chlorine
Atoms, and conversion products do not have catalytic activity.
-CHCl-CHCl-CH-, tail - tail structure-CHCl-CH2-CH2-CHCl-; generate a coupling disproportionation vinyl Results CH2 = CH-CHCl
-CH2-structure and allyl chloride-CH2-CH = CH-CHCl-CH2 and so on.
Generated in the PVC synthetic allyl chloride, chlorine and tertiary carbon double bond in its molecular chain structure instability, unstable cis
Sequence is: PVC within the molecular chain allyl chloride> tertiary carbon Chlorine> terminal allyl chloride> sec chlorine. PVC processing is easily degraded but because
The PVC molecular chain structure, there vegetable stearic acid is instability factors, such modification not be stabilized, and its decomposition temperature is about 130 ℃, but
PVC resin to be processed into useful articles, molding temperature to above 190 ℃. Therefore, you must add to its junction heat stabilizer
Improved structure for stabilization. Four types of heat stabilizers heat discoloration Comment
Ideal thermal stabilizer should also absorb HCL, remove the active site, the addition of a conjugated polyene chain, from the destruction of carbenium
Sub-salt, to prevent the auto-oxidation and other functions, without generating a catalytic degradation of PVC products. The plastic processing aid actual heat stabilizer due to
Has a different function and behave in a different thermal stability characteristics, can be divided into early-type, long type, intermediate type and versatile
Four categories.
1) cadmium, zinc soap is typical of early-type heat stabilizers, can quickly absorb HCL, and Cd, Zn in the catalyst effectively carboxylic
Replace PVC chain radical unstable chlorine atoms, thereby effectively suppressing the initial degradation and coloring, but because of consumption of fast transformation products CdC12, ZnC12, but also off the HCL PVC efficient catalysts, which will lead to the aluminium distearate degradation of PVC material suddenly becomes a vicious black, so
Long-term thermal stability. 2) barium, calcium soap is a typical long-term thermal stabilizers, absorption HCL function only and therefore can not effectively suppress coloring PVC,
But the transformation products BaC12, CaC12 does not have catalytic activity, does not cause a sudden black PVC, long-term thermal stability. 3) fatty acids, organic tin are intermediate, both absorbs HCL, can effectively replace PVC with chain carboxylate unstable chlorine
Atoms, and conversion products do not have catalytic activity.
The main types of PVC
1.pvc generally soft products.
You can use the extruder extruded hoses, cables, wires, etc.; utilize injection molding machine with a variety of molds can be made of plastic
(7740, -270.00, -3.37%) sandals, shoes, slippers, toys, auto parts and so on.
2.pvc film. pvc mixed with additives, plasticizers, the use antimony trioxide of three-roll or four-roll calender and formed into a predetermined thickness of a transparent or colored film,
This method of processing a film, a calendered film. You can also cut, heat processing, packaging bags, raincoats, tablecloths, curtains, inflatable toys. Wide transparent film can be used for greenhouses, plastic greenhouses and film use. The biaxially oriented thin
Film, suffered heat shrinkable properties, can be used for shrink packaging.
3.pvc coating products.
There is pvc artificial leather substrate confused spreads the cloth or paper, and then at 100 degrees or more plasticizing. Also available
In the first pvc calendered into a film with additives, and then laminated together with the substrate. No artificial leather substrate is directly from the rolling machine rolling into a certain thickness of the soft system sheet, and then the pressure on the pattern can be. Can be used to make leather suitcases, purses, book cover,
Sofa and car seat, as well as floor coverings, flooring materials for buildings.
4.pvc foam products.
Soft pvc mixing, adding the right amount titanium dioxide rutile of foaming agent made of sheet material, the foam molding of foam can be used for foam slippers
Sandals, insoles, and shockproof cushion packaging materials. Extruder can also be used as the basis of rigid pvc foam sheet and low profile, alternative timber trial, is a new construction material only.
5.pvc transparent sheet.
pvc impact modifier was added and calcium zinc stabilizer the organic tin stabilizer, mixing, plasticizing, rolling and a transparent sheet. Using thermal
Molding can be made thin transparent containers or for vacuum packaging, is an excellent packaging materials and decorative materials.
6.pvc hard board and sheet.
adding pvc stabilizers, lubricants and fillers, the kneaded, extruded with an extruder to a variety of hard tube diameter, shaped
Tubes, bellows, as the plumbing, water pipes, wire casing or stair railing. Good hot rolled sheets overlap will be
Made of rigid plates of various thicknesses. Sheet can be cut into desired shape and then use pvc welded by hot air welding
Various chemical resistant tanks, duct and containers.
7.pvc other.
Windows and doors with rigid shaped materials assembled. In some countries such as aluminum windows and wood windows and doors windows and doors occupy common market
You can use the extruder extruded hoses, cables, wires, etc.; utilize injection molding machine with a variety of molds can be made of plastic
(7740, -270.00, -3.37%) sandals, shoes, slippers, toys, auto parts and so on.
2.pvc film. pvc mixed with additives, plasticizers, the use antimony trioxide of three-roll or four-roll calender and formed into a predetermined thickness of a transparent or colored film,
This method of processing a film, a calendered film. You can also cut, heat processing, packaging bags, raincoats, tablecloths, curtains, inflatable toys. Wide transparent film can be used for greenhouses, plastic greenhouses and film use. The biaxially oriented thin
Film, suffered heat shrinkable properties, can be used for shrink packaging.
3.pvc coating products.
There is pvc artificial leather substrate confused spreads the cloth or paper, and then at 100 degrees or more plasticizing. Also available
In the first pvc calendered into a film with additives, and then laminated together with the substrate. No artificial leather substrate is directly from the rolling machine rolling into a certain thickness of the soft system sheet, and then the pressure on the pattern can be. Can be used to make leather suitcases, purses, book cover,
Sofa and car seat, as well as floor coverings, flooring materials for buildings.
4.pvc foam products.
Soft pvc mixing, adding the right amount titanium dioxide rutile of foaming agent made of sheet material, the foam molding of foam can be used for foam slippers
Sandals, insoles, and shockproof cushion packaging materials. Extruder can also be used as the basis of rigid pvc foam sheet and low profile, alternative timber trial, is a new construction material only.
5.pvc transparent sheet.
pvc impact modifier was added and calcium zinc stabilizer the organic tin stabilizer, mixing, plasticizing, rolling and a transparent sheet. Using thermal
Molding can be made thin transparent containers or for vacuum packaging, is an excellent packaging materials and decorative materials.
6.pvc hard board and sheet.
adding pvc stabilizers, lubricants and fillers, the kneaded, extruded with an extruder to a variety of hard tube diameter, shaped
Tubes, bellows, as the plumbing, water pipes, wire casing or stair railing. Good hot rolled sheets overlap will be
Made of rigid plates of various thicknesses. Sheet can be cut into desired shape and then use pvc welded by hot air welding
Various chemical resistant tanks, duct and containers.
7.pvc other.
Windows and doors with rigid shaped materials assembled. In some countries such as aluminum windows and wood windows and doors windows and doors occupy common market
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